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Halogen-substituted salicylhydroximate copper(II) metallacrowns: from synthesis and structures to novel applications |
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| Institution: | 1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, Russian Federation;2. Privolzhsky Research Medical University, 603005 Nizhny Novgorod, Russian Federation;3. A. M. Butlerov Institute of Chemistry, Kazan Federal University, 420008 Kazan, Russian Federation |
| Abstract: | New halogen-substituted salicylhydroximate copper(II) metallacrowns were synthesized from Cu(OAc)2 and the corresponding salicylhydroxamic acids. Their molecular structure was determined by single crystal X-ray diffraction. The compounds obtained represent the first members of the metallacrown family that can be used as components of active initiators for the photopolymerization of oligo-carbonate dimethacrylate by visible light. |
| Keywords: | copper(ii) metallacrowns organohalogen compounds salicylhydroxamic acids X-ray structure DFT calculations photo- polymerization of dimethacrylate |
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