The Ru(II)-supported heptatungstates [HXW7O28Ru(dmso)3]6-(X=P, As) |
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| Authors: | Bi Li-Hua Dickman Michael H Kortz Ulrich Dix Ina |
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| Affiliation: | International University Bremen, School of Engineering and Science, P.O. Box 750 561, 28725, Bremen, Germany. |
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| Abstract: | ![]()
The ruthenium(II)-supported heteropolyanions [HXW7O28Ru(dmso)3]6-(X=P, 1; As, 2) are composed of a Ru(dmso)3 group attached to an unprecedented heptatungstate fragment via two Ru-O-W bonds and one Ru-O-X bond, which represents a fundamentally novel mode of Ru-coordination to a polyoxoanion framework. Multinuclear 183W, 31P, 13C, and 1H NMR studies indicate high stability of 1 and 2 in solution. |
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