Dehydrogenation of compounds with weakened C-H bonds in the presence of platinum and palladium fullerides |
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| Authors: | G N Boiko Yu M Shul’ga O S Roshchupkina A S Lobach N F Gol’dshleger |
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| Institution: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia |
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| Abstract: | Coordinated fullerene acts as a hydrogen acceptor in reactions with compounds having weakened C-H bonds (1,4-dihydropyridine and 9,10-dihydroanthracene). Metal fullerides are the dehydrogenation catalysts. They activate the C-H bonds of dihydroanthracene and diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate in positions 9,10 and 1,4, respectively. No activation of norbornane carbon-hydrogen bonds with metal fullerides was observed under mild conditions. |
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