Locating the cyclopentano cousins of the cucurbit[n]uril family |
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| Authors: | Wu Feng Wu Li-Hui Xiao Xin Zhang Yun-Qian Xue Sai-Feng Tao Zhu Day Anthony I |
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| Institution: | Chemistry, School of PEMS, University of New South Wales at ADFA, Australian Defence Force Academy, Canberra, ACT 2600, Australia. |
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| Abstract: | The synthesis of the first family of fully substituted cucurbitn]uril is discussed, and the structural features of precursor glycolurils are highlighted in their importance to achieving higher homologues. The members of the family, where n = 5-7, have been fully characterized, and increased binding affinities have been identified for dioxane in CyP(6)Q6] and adamantyl NH(3)(+) in CyP(7)Q7]. A higher homologue is indicated but not conclusively identified. |
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