Relationship between chain termination rate constant and conversion in radical polymerization |
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Authors: | Katsukiyo Ito |
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Abstract: | At low and high conversions, the chain termination rate constant for bimolecular termination between polymeric radicals given by kt = AtDs, where At is a constant and Ds is the diffusion constant of radical chain end, is completely correct. This termination rate constant does not depend on solution viscosity, but conversion. |
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