Synthesis of functionalized pentacenes from isobenzofurans derived from C-H bond activation |
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| Authors: | Kuninobu Yoichiro Seiki Takayuki Kanamaru Shunsuke Nishina Yuta Takai Kazuhiko |
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| Affiliation: | Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Kita-ku, Okayama 700-8530, Japan. kuninobu@cc.okayama-u.ac.jp |
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| Abstract: | The synthesis of unsymmetric functionalized pentacenes from 1,4-anthraquinones and functionalized isobenzofurans, which were prepared by transformation via C-H bond activation, was successfully accomplished. Examples of the synthesis of pentacenes with functional groups at the 5-position are still rare. These obtained functionalized pentacenes are highly soluble in hexane, toluene, and THF. |
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