Electronic structure and X-ray spectra of nickel(II) dithiolate chelate complexes |
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| Authors: | L. N. Mazalov N. A. Kryuchkova G. K. Parygina O. A. Tarasenko S. V. Trubina |
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| Affiliation: | 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division,Russian Academy of Sciences,Novosibirsk,Russia |
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| Abstract: | Nickel(II) dithiocarbamate and dithiophosphinate complexes were studied by X-ray and X-ray photoelectron spectroscopy. The X-ray emission and absorption spectra of Ni(II) compounds were interpreted in terms of quantum-chemical model calculations of the electronic spectrum of the complexes. The electronic structure of nickel(II) dithiolates was analyzed on the basis of the experimental and theoretical data. |
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