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Corrosion behaviors in physiological solution of cerium conversion coatings on AZ31 magnesium alloy
Authors:Xiufang CuiYuyun Yang  Erbao LiuGuo Jin  Jinggao ZhongQingfen Li
Institution:a School of Materials Science and Chemical Engineering, Harbin Engineering University, 145 Nantong St., Harbin 150001, China
b Center for Biomedical Materials and Engineering, School of Materials Science and Chemical Engineering, Harbin Engineering University, 145 Nantong St., Harbin 150001, China
Abstract:In this paper, a non-toxic Ce-based conversion coating was obtained on the surface of bio-medical AZ31 magnesium alloys. The micro-morphology of the coating prepared with optimal technical parameters and immersed in physiological solution (Hank's solution) in different time was observed by scanning electron microscopy (SEM), composition of the cerium conversion coating and corrosion products in Hank's solution were characterized by X-ray photoelectron spectroscopy (XPS) and energy dispersive spectroscopy (EDS), respectively. In addition, the corrosion property in Hank's solution was studied by electrochemical experiment and immersion test. The results show that the dense Ce-based conversion coating is obtained on the surface of AZ31 magnesium alloys in optimal technical parameters and the conversion coating consists of a mass of trivalent and tetravalent cerium oxides. The cerium conversion coating can provide obvious protection of magnesium alloys and can effectively reduce the degradation speed in Hank's solution. Also the degradation products have little influence on human body.
Keywords:Hank's solution  Corrosion  AZ31 magnesium alloy  Cerium conversion coating
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