| S-烷基-O-(邻烷氧基羰基苯基)-硫(赶)代磷酰胺的NMR研究 |
| |
| 引用本文： | 李丽云,裘鉴卿,鲁晓明,袁汉珍,沈联芳.S-烷基-O-(邻烷氧基羰基苯基)-硫(赶)代磷酰胺的NMR研究[J].波谱学杂志,1984,1(4):319-325. |
| |
| 作者姓名： | 李丽云 裘鉴卿 鲁晓明 袁汉珍 沈联芳 |
| |
| 作者单位： | 中国科学院武汉物理研究所 |
| |
| 摘 要： | 本工作记录了六种通式为H2N RS P=O-O-COOR'(R=Me,Et,i-Pr,n-Pr;R'=Me,Et,i-Pr)的有机磷农药的1H、13C、31P NMR谱及13C,1H异核化学位移相关谱。确定了各1H、13C、31P的化学位移值和1H-1H、31P-1H、31P-13C的偶合常数。讨论了核磁参数与分子结构和运动以及31P化学位移与生物活性之间的关系。
|
| 收稿时间： | 1984-01-18 |
NMR STUDY ON S-ALKYL-O-(O-ALKOXYCARBONYLPHENYL) PHOSPHORAMIDOTHIOLATE |
| |
| Li Liyun,Qiu Hanging,La Xiaoming,Yuan Hanzhen,Shen Lianfang.NMR STUDY ON S-ALKYL-O-(O-ALKOXYCARBONYLPHENYL) PHOSPHORAMIDOTHIOLATE[J].Chinese Journal of Magnetic Resonance,1984,1(4):319-325. |
| |
| Authors: | Li Liyun Qiu Hanging La Xiaoming Yuan Hanzhen Shen Lianfang |
| |
| Institution: | Wuhan Institute of Physics, Academia Sinica |
| |
| Abstract: | In this paper,1H 13C, 31P NMR spectra of 6 phosphoramidothiolates of genera formula H2N RS P=O-O-COOR'(R=methyl, ethyl, isopropyl,propyl;R'=methyl, ethyl, isopropyl) and two-dimensional 13C-1H heteronuclear chemical shift correlation NMR spectroscopy were recorded. 1H,13C, 31P chemical shifts and 1H-1H,31P-1H,31P-13C different kinds of coupling contant were determined. The relations between of NMR parameters and molecular motion and between 31P chemical shifts and the insecticidal activity were discussed. |
| |
| Keywords: | |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《波谱学杂志》浏览原始摘要信息 |
| 点击此处可从《波谱学杂志》下载免费的PDF全文 |
|
