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Iridoids from Viburnum cylindricum
Authors:Xiao‐Zhen Chen  Hua‐Fang Wu  Guo‐You Li  Sheng‐Ming Lu  Bo‐Gang Li  Dong‐Mei Fang  Guo‐Lin Zhang
Affiliation:1. Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041, P. R. China, (phone: +86‐28‐85225401;2. fax: +86‐28‐85225401);3. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, P. R. China;4. Graduate University of the Chinese Academy of Sciences, Beijing 100049, P.?R. China
Abstract:
Two new iridoids, methyl (+)‐rel‐(1R,3S,4R,5R,8R,9R)‐1,3,4,5,8,9‐hexahydro‐8‐hydroxy‐3‐methoxy‐2H‐1a,2‐dioxacyclopent[cd]indene‐4‐carboxylate ( 1 ) and methyl (+)‐rel‐(1R,3S,4S,5R,8R,9R)‐1,3,4,5,8,9‐hexahydro‐8‐hydroxy‐3‐methoxy‐2H‐1a,2‐dioxacyclopent[cd]indene‐4‐carboxylate ( 2 ), were isolated from Viburnum cylindricum along with 14 known compounds. Their structures were determined by spectroscopic analyses. This type of iridoids bearing a MeO group at C(3) was discovered for the first time.
Keywords:Viburnum cylindricum  Iridoids  α  ‐Gardiol
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