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Direct Electrochemistry of Glucose Oxidase at Carbon Nanotube‐gold Colloid Modified Electrode with Poly(diallyldimethylammonium chloride) Coating
Authors:Yan‐Li Yao  Kwok‐Keung Shiu
Institution:Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Kowloon, Hong Kong
Abstract:Glucose oxidase showed direct electrochemical transfer at glassy carbon electrodes immobilized with carbon nanotube‐gold colloid (CNT‐Au) composites with poly(diallydimethylammonium chloride) (PDDA) coatings. The modified electrode (GC/CNT/Au/PDDA‐GOD) was employed for the amperometric determination of glucose. Under optimal conditions, the biosensor displayed linear response to glucose from 0.5 to 5 mM with a sensitivity of 2.50 mA M?1 at an applied potential of ?0.3 V (vs. Ag|AgCl reference).
Keywords:Carbon nanotubes  Gold nanoparticles  Poly(diallyldimethylammonium chloride)  Glucose biosensor  Direct electrochemistry
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