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Electrochemical Characterization of Self‐Assembled Monolayer of a Novel Manganese Tetrabenzylthio‐Substituted Phthalocyanine and Its Use in Nitrite Oxidation |
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| Authors: | Fungisai Matemadombo Sophie Griveau Fethi Bedioui Tebello Nyokong |
| Affiliation: | 1. Rhodes University, Department of Chemistry, PO Box 94, 6140 Grahamstown, South Africa;2. Unité Pharmacologie Chimique et Génétique, CNRS 8151, INSERM 640, Ecole Nationale Supérieure de Chimie de Paris, Paris Descartes. ENSCP, 11 rue Pierre et Marie Curie, 75231?Paris cedex 05, France |
| Abstract: | Manganese phthalocyanine MnPc(SPh)4 has been synthesized and used to form self assembled monolayers on gold electrodes. The well packed SAM monolayer was characterized by analyzing the blocking of a number of Faradic processes by cyclic voltammetry, evaluating the electrical characteristics of the modified electrode by electrochemical impedance and imaging the modified surface by electrochemical scanning microscopy. Finally, MnPc(SPh)4‐SAM modified electrode displayed an electrocatalytic behavior toward the oxidation of nitrite. |
| Keywords: | Manganese phthalocyanine Cyclic voltammetry Self‐assembled monolayer Impedance spectroscopy Nitrite oxidation Electrochemical scanning microscopy |