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Secondary Kinetic Isotope Effects as Probes of Environmentally‐Coupled Enzymatic Hydrogen Tunneling Reactions |
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| Authors: | Sam Hay Dr. Jiayun Pang Dr. Phillip J. Monaghan Dr. Xi Wang Dr. Rhiannon M. Evans Michael J. Sutcliffe Prof. Rudolf K. Allemann Prof. Nigel S. Scrutton Prof. |
| Affiliation: | 1. Manchester Interdisciplinary Biocentre, Faculty of Life Sciences, University of Manchester, 131 Princess Street, Manchester M1 7DN (UK), Fax: (+44) 161 306 8918;2. Manchester Interdisciplinary Biocentre, School of Chemical Engineering and Analytical Science, University of Manchester, 131 Princess Street, Manchester M1 7DN (UK);3. School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT (UK), Fax: (+44) 29 208 79014 |
| Abstract: | |
| Keywords: | catalysis enzyme kinetic isotope effects quantum chemistry reaction mechanisms |