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Thermal,spectral and biological properties of Zn(II) complex compounds with phenazone
Authors:Erika Szunyogová  Katarína Györyová  Daniela Hudecová  Lenka Piknová  J. Chomič  Zuzanna Vargová  V. Zeleňák
Affiliation:(1) Department of Biophysics, Institute of Experimental Physics, Slovak Academy of Science, Košice, Slovak Republic, 043 53, Watsonova 47;(2) Department of Inorganic Chemistry, P. J. Šafarik University, Košice, Slovak Republic, 041 54, Moyzesova 11;(3) Department of Biochemistry and Microbiology, Slovak University of Technology, Bratislava, Slovak Republic, 812 37, Radlinského 9
Abstract:
The thermal decomposition of the complexes Zn(form)2⋅2phen (I), Zn(ac)2⋅2phen (II), Zn(prop)2⋅2phen (III), Zn(but)2⋅2phen (IV), where phen=phenazone, form=formiate, ac=acetate, prop=propionate, but=butyrate has been studied in air by TG/DTG and DTA methods. The possible mechanism of the thermal decomposition was proposed. The final product of thermal decomposition was ZnO. IR data show unidentate coordination of carboxylate group to Zn(II) ion. The complexes were tested against various strains of microorganisms and their efficiency decrease in the sequence yeasts >bacteria>filamentous fungi.
Keywords:biological properties  IR spectra  phenazone  thermal properties  zinc(II) complexes
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