| Crystal Structure of [Cd（pom）2Cl2] |
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| 引用本文： | 吴文士,董美斌,等.Crystal Structure of [Cd（pom）2Cl2][J].结构化学,1996,15(4):330-332. |
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| 作者姓名： | 吴文士 董美斌 等 |
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| 作者单位： | [1]DepartmentofChemistry,Hua－qiaoUniversity,Fujian,Ch [2]DepartmentofChemistry,Hua－qia |
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| 摘 要： | ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ［Ｃｄ（ｐｏｍ）_２Ｃｌ_２］ＷｕＷｅｎ－Ｓｈｉ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｓｔｒｙ，Ｈｕａ－ｑｉａｏＵｎｉｖｅｒｓｉｔｙ，Ｆｕｊｉａｎ，Ｃｈｉｎａ，３６２０１１）ＤｏｎｇＭｅｉ－Ｂｉｎ；ＬｉＳｏｎｇ－Ｘｉａ...
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| 关 键 词： | 晶体结构 镉配合物 3－甲基－4－硝基氧化吡啶 二氯化镉 |
Crystal Structure of[Cd(pom)_2Cl_2] |
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| Wu Wen-Shi.Crystal Structure of[Cd(pom)_2Cl_2][J].Chinese Journal of Structural Chemistry,1996,15(4):330-332. |
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| Authors: | Wu Wen-Shi |
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| Abstract: | Catena-bis (3-methyl-4-nitropyridine N-oxide ) cadmiumdichloride],Cd(C_6H_6N_2O_3)_2Cl_2], M_r= 491. 56, monoclinic , P2_1, a= 3. 799 (3), b= 29. 231 ( 9),c=7. 679(5) A, β=100. 19(6)°, V=839. 4 A￣3, Z=2, D_c= 1. 94 g/cm￣3, λ(MoKa)= 0. 71069 A, F(000) =484, P(MoKa) = 16. 5 cm￣(-1), final R=0. 038 for 1202 Observed reflections, T= 296K. The Cd atom is octahedrally coordinated by two O atoms from the trans 3-methyl-4-nitropyridine N-oxide (pom) ligands in the axial positions and four Cl atoms lying in the equatorial plane. The coordination octahedra form chains along the short a axis by edge sharing through the Cl atoms. |
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| Keywords: | cadmium complex nonlinear optical material one-dimensional coordination crystal structure |
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