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LLX separation of carrier-free,94,95,97,103Ru,93,94,95,96,99mTc and95,96Nb produced in alpha-particle activated molybdenum by TOA
Authors:S Lahiri  B Mukhopadhyay  N R Das
Institution:(1) Nuclear and Analytical Chemistry Laboratory, Department of Chemistry, University of Burdwan, 713 104 Burdwan, India;(2) Nuclear Chemistry Division, Saha Institute of Nuclear Physics, I/AF, Bidhannagar, 700064 Calcutta, India
Abstract:A radiochemical charged particle activation procedure for the simultaneous production of carrier-free radioisotopes of more than one element in a single target and their subsequent separation through LLX has been demonstrated. The carrier free isotopes,95,96Nb,93,94,95,96,99mTc and94,95,97,103Ru formed through Mo(agr,agrpxn), Mo(agr,pxn) and Mo(agr,xn) nuclear reactions with 40 MeV agr-particle as detected by nondestructive gamma-ray spectroscopy, have been effectively separated through LLX using TOA as an anionic extractant. Separation of the bulk matrix of molybdenum from the carrier free products has been monitored radiometrically using isotopic93,99mMo formed through the Mo(agr,agrxn) reaction, as radioindicators for the target element. Purity of the separated carrier free radionuclide has been verified by gamma-ray spectrometry.
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