|
|||||
|
|
Increased catalytic activity of surface-immobilized palladium complexes in the fluorogenic deprotection of an alloc-derivatized coumarin |
|
| Authors: | Fernandes Antony Hensenne Peter Mathy Bertrand Guo Weiming Nysten Bernard Jonas Alain M Riant Olivier |
| Institution: | Institute of Condensed Matter and Nanosciences, Université catholique de Louvain, Place Louis Pasteur 1, 1348 Louvain-la-Neuve, Belgium. |
| Abstract: | Catalytic surfaces have been prepared by complexation of palladium on self-assembled terpyridine monolayers on silicon. A reaction-based fluorogenic probe was developed to allow facile visualization of the catalytic potential of the surface. Superior activity of the immobilized catalyst compared with the homogeneous control reactions is demonstrated. |
| Keywords: | fluorogenic reactions heterogeneous catalysis monolayers palladium silicon surface chemistry |
| 本文献已被 PubMed 等数据库收录！ | |