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Fluorescent composite hydrogels of metal-organic frameworks and functionalized graphene oxide
Authors:Lee Ji Ha  Kang Sunwoo  Jaworski Justyn  Kwon Ki-Young  Seo Moo Lyong  Lee Jin Yong  Jung Jong Hwa
Institution:Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Jinju 660-701, Korea.
Abstract:GO MOFs! Azobenzoic acid functionalized graphene (A-GO) can act as a structure-directing template that influences hydrogel formation together with metal-organic frameworks (MOFs). Zn(2+) MOFs of pyridine derivatives work as framework linkers between the A-GO sheets (MOF-A-GO, see figure). MOF-A-GO exhibits a strong fluorescence enhancement upon gel formation. In addition, MOF-A-GO selectively recognizes trinitrotoluene.
Keywords:graphene oxide  gels  metal–organic frameworks  trinitrotoluene
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