Synthesis of cuprous oxide nanocomposite electrodes by room-temperature chemical partial reduction |
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Authors: | Park Kyung-Soo Seo Seung-Deok Jin Yun-Ho Lee Seung-Hun Shim Hyun-Woo Lee Du-Hee Kim Dong-Wan |
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Institution: | Department of Materials Science & Engineering, Ajou University, Woncheon-dong, San 5, Yeongtong-gu, Suwon 443-749, Korea. |
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Abstract: | We demonstrate a template-free synthetic approach for the preparation of a highly conductive Cu/Cu(2)O nanocomposite electrode by a chemical reduction process. Cu(2)O octahedra were prepared through chemical dehydrogenation of as-synthesized Cu(OH)(2) nanowire precursors. To provide a sufficiently electron-conducting network, the Cu(2)O particles were transformed into Cu/Cu(2)O nanocomposites by an intentional reduction process. The Cu/Cu(2)O nanocomposite electrodes showed enhanced cycling performance compared to Cu(2)O particles. Furthermore, their rate capabilities were superior to those of their mechanically mixed Cu/Cu(2)O counterparts. This enhanced electrochemical performance of the hybrid Cu/Cu(2)O nanocomposites was ascribed to the formation of homogeneous nanostructures, offering an efficient electron-transport path provided by the presence of highly dispersed Cu nanoparticles. |
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