Primary amines via electrophilic amination of organometallic compounds with o-(diphenylphosphinyl)hydroxylamine |
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Authors: | Gernot Boche Michael Bernheim Wolfgang Schrott |
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Institution: | Fachbereich Chemie der Universität Marburg, Hans-Meerwein-Straße, D-3550 Marburg, Germany |
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Abstract: | It is shown that O-(diphenylphosphinyl)hydroxylamine transforms all kinds of “carbanions” into primary amines; best yields are received with “stabilized anions”, e.g. of the benzylic type. |
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