The static dielectric constant of solutions of water inn-alcohols at 15, 25, 35, and 45°C |
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Authors: | Alessandro D'Aprano Dorina I Donato Eugenio Caponetti |
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Institution: | (1) Istituto di Chimica Fisica dell' Università di Palermo, Via Archirafi 26, 90123 Palermo, Italy |
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Abstract: | Dielectric constants (measured at 1 MHz) are reported for solutions of water (concentration range 0 to 0.2 mole fraction)
in 1-propanol at 25°C, and in 1-butanol, 1-pentanol, and 1-hexanol at 15, 25, 35, and 45°C. These results, together with literature
values for solutions of water in methanol, ethanol, 1-heptanol, and 1-octanol, show that water interacts with alcohols in
at least two ways: (1) it can participate in the formation of dynamic hydrogen-bonded chains, thereby raising the polarizability;
(2) it can form relatively stable structures such as H2O(ROH)4 which have zero net dipole moment and consequently diminish volume polarizability. For C
n
H
2n+1
OH alcohols,n≥4, most of the initially added water forms complexes: consequently, addition of water to these alcohols lowers the dielectric
constant. |
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Keywords: | Dielectric constants of water inn-alkanol solutions water-alcohol interaction Kirkwood correlation factor hydrogen-bonded structures water-alcohol complexes |
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