The velocity correlation function for the Lorentz gas |
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Authors: | R. G. Cole T. Keyes |
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Affiliation: | (1) Department of Chemistry, Boston University, 02215 Boston, Massachusetts;(2) Present address: AT&T Bell Laboratories, 07733 Holmdel, New Jersey |
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Abstract: | The results of variational solutions of the repeated ring and self-consistent repeated ring equations for the two-and three-dimensional overlapping Lorentz gas (LG), as formulated in a previous report, are presented. Calculations of the full velocity correlation function (VCF) for the 2D LG, including long-time tails, are compared with those from molecular dynamics. The trial functions chosen lead to predictions for the long-time tails that improve as the density of the scatterers is increased. At a value of 0.24 for* (=2, where is the density and the radius of scatterers), the self-consistent amplitudes of the long-time tail are within 40% of the molecular dynamics. A limited number of 3D results for the short-time behavior of the repeated ring VCF are presented. The 3D solutions agree with the molecular dynamics to within 10%. |
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Keywords: | Kinetic theory random media Lorentz model self-consistent repeated ring theory long-time tails |
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