An analytic formula of one-dimensional Franck-Condon factors for linear harmonic oscillators |
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Authors: | Kuo-mei Chen Cheng-chih Pei |
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Abstract: | With the aid of an addition theorem for harmonic oscillator wave functions, the Franck-Condon factors between two displaced linear oscillators with unequal vibrational frequencies are transformed into an analytic form which is programmable for numerical evaluations. Franck-Condon factors for the A1Σu+-X1Σg+ system and the B1Πu-X1Σg+ system of 7Li2 are calculated via this analytic formula. |
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