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Multistimuli-responsive hydrogels of poly(2-acrylamido-2-methyl-1-propanesulfonic acid) containing graphene
Authors:Valeria Alzari  Daniele Nuvoli  Roberta Sanna  Laura Peponi  Massimo Piccinini  Silvia Bittolo Bon  Salvatore Marceddu  Luca Valentini  Jose Maria Kenny  Alberto Mariani
Affiliation:1. Dipartimento di Chimica e Farmacia, Università degli Studi di Sassari e Unità locale INSTM, Via Vienna 2, 07100, Sassari, Italy
2. Institute of Polymer Science and Technology (ICTP-CSIC), Calle Juan de la Cierva 3, 28006, Madrid, Spain
3. Porto Conte Ricerche S.r.l., SP 55 km 8.400 Loc., Tramariglio, 07041, Alghero (SS), Italy
4. Civil and Environmental Engineering Department, INSTM Research Unit, University of Perugia, Strada di Pentima 4, 05100, Terni, Italy
5. Consiglio Nazionale delle Ricerche (CNR), Istituto di Scienze delle Produzioni Alimentari (ISPA), Li Punti (Reg. Baldinca), Traversa La Crucca, 07100, Sassari, Italy
Abstract:Nanocomposite hydrogels of poly(2-acrylamido-2-methyl-1-propanesulfonic acid) containing graphene were prepared by radical polymerization. Their swelling properties in response to ionic strength and electrical stimuli were assessed. Graphene was obtained through an easy and convenient method lately developed by our research group, which consists in the exfoliation of graphite by sonicating it in a proper solvent medium. It was found that the graphene content influences the swelling properties of hydrogels; in particular, those containing graphene swell more than the filler-free ones; graphene content influences also the swelling ratio variation between the swollen and deswollen states.
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