Studies of the complex formation of silver (I) ion with 18-crown-6 in H2O-DMSO mixtures by calorimetry |
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| Authors: | Usacheva T R Lendencov S F Sharmin V A |
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| Institution: | (1) Ivanovo State University of Chemistry and Technology, 153460 Ivanovo, F. Engels av., 7, Russia |
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| Abstract: | The thermodynamic parameters (DrG0, Dr
H
0, TDr
S
0) of the reaction of Ag18C6]+ complex formation were obtained for a wide range of H2O-DMSO mixtures from the calorimetric data at 298.15 K. The relation between the thermodynamic parameters of complex formation
and solvation of each reagent was investigated.
This revised version was published online in July 2006 with corrections to the Cover Date. |
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| Keywords: | complex formation silver (I) ion 18-crown-6 mixed solvents enthalpy |
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