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Excess Gibbs energy of mixing of the systems H2O-LiCl-Na2SO4 and H2O-CsCl-Na2SO4 at 25°C
Authors:Robinson  R. A.
Affiliation:(1) State University of New York at Binghamton, Binghamton, New York;(2) Present address: University of Florida, Gainesville, Florida
Abstract:
The osmotic coefficients of aqueous solutions of lithium chloride+sodium sulfate and cesium chloride+sodium sulfate at 25°C have been measured. Interaction coefficients have been calculated and also the excess Gibbs energy of mixing. A correlation is found between the binary interaction coefficients and the Pauling cation radius of the alkali halide component.
Keywords:Cesium chloride  excess energy of mixing  lithium chloride  mixed solutions  sodium sulfate
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