| 有机-无机杂化四核镍取代的夹心型砷钨酸盐的合成与晶体结构 |
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| 引用本文： | 赵俊伟,罗婕,史岽瑛,栗玉叶.有机-无机杂化四核镍取代的夹心型砷钨酸盐的合成与晶体结构[J].化学研究,2011,22(4):15-19. |
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| 作者姓名： | 赵俊伟 罗婕 史岽瑛 栗玉叶 |
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| 作者单位： | 1. 河南大学化学化工学院,分子与晶体工程研究所,河南开封475004
2. 河南大学化学化工学院,分子与晶体工程研究所,河南开封475004;河南大学基础实验教学中心,河南开封475004 |
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| 摘 要： | 在水热条件下,合成了-种有机-无机杂化四核镍取代的夹心型砷钨酸盐Ni(detaH)2(H2O)]2Ni(deta)2]Ni4(H2O)2(B-α-AsW9O34)2]·4H2O(deta=二乙烯三胺),并借助IR光谱和X射线单晶衍射对其结构进行了表征.标题化合物属于正交晶系,Pbca空间群,晶胞参数:a=2.16...
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| 关 键 词： | 多金属氧酸盐 砷钨酸盐 镍簇 夹心型化合物 |
Synthesis and crystal structure of an organic-inorganic hybrid tetranickel substituted sandwich-type arsenotungstate |
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| ZHAO Jun-wei,LUO Jie,SHI Dong-ying,LI Yu-ye.Synthesis and crystal structure of an organic-inorganic hybrid tetranickel substituted sandwich-type arsenotungstate[J].Chemical Research,2011,22(4):15-19. |
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| Authors: | ZHAO Jun-wei LUO Jie SHI Dong-ying LI Yu-ye |
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| Institution: | ZHAO Jun-wei1,LUO Jie1,2,SHI Dong-ying1,LI Yu-ye1(1.Institute of Molecular and Crystal Engineering,College of Chemistry and Chemical Engineering,Henan University,Kaifeng 475004,Henan,China,2.Basic Experiment Teaching Center,China) |
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| Abstract: | An organic-inorganic hybrid tetranickel substituted sandwich-type arsenotungstate Ni（detaH）2（H2O）]2Ni（deta）2]Ni4（H2O）2（B-α-AsW9O34）2]·4H2O has been hydrothermally synthesized and structurally characterized by IR spectrum and X-ray single-crystal diffraction.The title compound crystallizes in the orthorhombic space group Pbca with a = 2.168 8（3） nm,b = 1.943 5（3） nm,c = 2.188 6（3） nm,V = 9.225（2） nm3,Z = 4,Dc = 4.122 g/cm3,GOOF = 1.146,R1 = 0.034 8,wR2 = 0.081 0.X-ray structural analysis indicates that the title compound consists of 1 tetranickel substituted polyoxoanion Ni4（H2O）2（B-α-AsW9O34）2]10-,2 supporting Ni（detaH）2（H2O）]4＋ cations,1 discrete Ni（deta）2]2＋ cation and 4 lattice water molecules. |
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| Keywords: | polyoxometalate arsenotungstate nickel cluster sandwich-type complex |
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