Studies of poly-yne polymers containing transition metals in the main chain : III. Synthesis and characterization of a poly-yne polymer containing mixed metals in the main chain,期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Studies of poly-yne polymers containing transition metals in the main chain : III. Synthesis and characterization of a poly-yne polymer containing mixed metals in the main chain,

Authors:	K. Sonogashira S. Kataoka S. Takahashi N. Hagihara

Affiliation:	The Institute of Scientific and Industrial Research, Osaka University, Suita, Osaka, 565 Japan

Abstract:	By the reaction of trans-(PBu₃)₂Pt(CCCCH)₂ with trans-(PBu₃)₂PdCl₂, the title polymer, (II), has been prepared and characterized by spectral and analytical data. The alternating regularity of the metal arrangement in II was confirmed by the selective formation of the trinuclear complex trans,trans,trans-ClPd(PBu₃)₂?CCC CPt(PBu₃)₂?CC-CCPd(PBu₃)₂(XXIII), in the depolymerization by trans- (PBu₃)₂PdCl₂ using CuI as catalyst in XXNEt₂.

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