Ruthenium complexes containing group 5b donor ligands : Part VII. Rearrangement reactions of some ruthenium (II) complexes containing triphenylphosphine,tri-p-tolylphosphine or ethyldiphenylphosphine ligands. |
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| Authors: | P.W. Armit W.J. Sime T.A. Stephenson L. Scott |
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| Affiliation: | Department of Chemistry, University of Edinburgh, Edinburgh EH9 3JJ Great Britain |
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| Abstract: | ![]()
As for [RuCl2(PPh33], carbonylation of [RuCl2(PR3)3] [PR3 = P(p-tolyl)3, PEtPh2) in N,N 1-dimethylformamide (dmf) gives [Ru(CO)Cl2 (dmf) (PR3)2] (II). For PR3 = PEtPh2, rearrangement of (II) in various solvents gives inseparable mixtures (31P evidence) but for PR3 = P(p-tolyl)3 [Ru2(CO)2Cl4-{P(p-tolyl)3}3]is obtained. Reaction of [Ru(CO)Cl2 (dmf) - {P(p-tolyl)3}2] with [RuCI2{(P(p-tolyl)3}3] (1:1 mol ratio) gives [Ru2 (CO) Cl4 {P (p-tolyl)3}4] whereas reaction of [Ru (CO) Cl2 (dmf) - (PPh32] with (Rul2 {P (p-tolyl)3}3] gives [Ru2(CO)Cl4 (PPh3)2] - {P(p-tolyl)3}2] - Reaction of [RuCl2 {P(p-tolyl)3}3] with CS2 gives the related [Ru2Cl4(CS) {P(p-tolyl)3}4] and [{RuCl2(CS)}P(p-tolyl)3{2}2] whereas [RuCl2(PEtPh2)3] and CS2 produce [RuCl2(S2CPEtPh2) (PEtPh2)2]CS2 and [Ru2Cl4(CS)2(PEtph2)3]. |
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