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Synthesis and structure of a novel MoFe_4S_4 cubane-like cluster (Me_3PhCH_2N)_2[MoFe_4S_4(SC_6H_(11))_7]
作者姓名:陈昌能  邓玉恒  洪茂椿  温庭斌  张纯喜  刘秋田  卢嘉锡  陈小明  康北笙  周忠远  麦松威
作者单位:State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,Chin
基金项目:ProjectsupportedbytheNationalNaturalScienceFoundationofChinaandtheClimbingProgram———StateKeyProjectfor FundamentalResearchinChina,andHongKongResearchGrantsCouncil(EarmarkedGrantNo .CUHK .311/ 94p)
摘    要:Itiswellknownthatinnaturetheactivationandreductionofdinitrogeninairtoammoniaarecatalyzedbynitrogenaseatambienttemperatureandpressure.ThemaincomponentsoftheactiveclusterofMoFeproteininnitrogenaseareMcluster(MoFe7S9cluster)andPcluster(Fe8S8cluster)1].Inthel…


Synthesis and structure of a novel MoFe_4S_4 cubane-like cluster (Me_3PhCH_2N)_2[MoFe_4S_4(SC_6H_(11))_7]
CHEN Changneng,DENG Yuheng HONG Maochun,WEN Tingbin ZHANG Chunxi,LIU Qiutian,LU Jiaxi.Synthesis and structure of a novel MoFe_4S_4 cubane-like cluster (Me_3PhCH_2N)_2[MoFe_4S_4(SC_6H_(11))_7][J].Science in China(Chemistry),1998(3).
Authors:CHEN Changneng  DENG Yuheng HONG Maochun  WEN Tingbin ZHANG Chunxi  LIU Qiutian  LU Jiaxi
Abstract:
Keywords:molybdenum iron sulfur cluster  single cubane cluster  crystal structure  iron cluster  
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