FEM study of NOW and NO2W adsorption system

Nitric oxide adsorption on tungsten and nitric dioxide adsorption on tungsten have been investigated by the FEM method. When NO or NO₂ adsorbs gradually on W at 300 K and at 80 K, the FEM patterns which appear at first are found to be similar to those which appear in N₂ adsorption on W. In the case of NO adsorption on W at 80 K, with further exposure, no further change of the FEM patterns is observed. However, in the cases of NO adsorption on W at 300 K, NO₂ adsorption on W at 300 K, and NO₂ adsorption on W at 80 K, further changes of the FEM patterns are observed with further exposure, and the FEM pattern which is obtained at the saturated state is found to be similar to the FEM pattern which appears at the saturated state of O₂ adsorption on W. From the above results it is suggested that NO and NO₂ dissociate on W at 300 and at 80 K.