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Effect of hydration on the luminescence properties of 2,2-difluoro-4-methylnaphto[2,1-e]-1,3,2-dioxaborine. Quantum chemical modeling and experiment |
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| Authors: | Fedorenko E V L’vov I B Vovna V I Shlyk D Kh Mirochnik A G |
| Institution: | 1.Institute of Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022, Vladivostok, Russian Federation ;2.Far-Eastern State University, 8 ul. Sukhanova, 690950, Vladivostok, Russian Federation ; |
| Abstract: | The effect of hydration on the spectral luminescence properties of solutions of 2,2-difluoro-4-methylnaphto2,1-e]-1,3,2-dioxaborine in organic solvents is studied. Quenching of luminescence and color changes of the solutions associated with hydration of luminophore molecules were observed. Quantum chemical modeling of the structure of the hydrate complex is carried out. |
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