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A Targeted Review of Current Progress,Challenges and Future Perspective of g-C3N4 based Hybrid Photocatalyst Toward Multidimensional Applications
Authors:Asif Hayat  Muhammad Sohail  Usama Anwar  T A Taha  H I A Qazi  Amina  Zeeshan Ajmal  Abdullah G Al-Sehemi  Hamed Algarni  Ahmed A Al-Ghamdi  Mohammed A Amin  Arkom Palamanit  W I Nawawi  Emad F Newair  Yasin Orooji
Institution:1. College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, 321004, Zhejiang PR, China;2. Yangtze Delta Region Institute (Huzhou), University of Electronic Science and Technology of China, Huzhou, 313001 P.R. China

These authors are contributed equally to the formation of this article.;3. Soochow Institute for Energy and Materials Innovations, College of Energy, Soochow University, Suzhou, 215006 China;4. Physics Department, College of Science, Jouf University, P.O. Box 2014, Sakaka, Saudi Arabia

Physics and Engineering Mathematics Department, Faculty of Electronic Engineering, Menoufia University, Menouf, 32952 Egypt;5. College of Optoelectronic Engineering, Chongqing University of Posts and Telecommunications, Chongqing, 400065 China;6. Department of Physics, Bacha Khan University Charsadda, Pakistan;7. School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, 710072 Xian, PR China;8. Research Center for Adv. Mater. Science (RCAMS), King Khalid University, P.O. Box 9004, Abha, 61413 Saudi Arabia

Department of Chemistry, College of Science, King Khalid University, P.O. Box 9004, Abha, 61413 Saudi Arabia;9. Research Center for Adv. Mater. Science (RCAMS), King Khalid University, P.O. Box 9004, Abha, 61413 Saudi Arabia

Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, 61413 Saudi Arabia;10. Department of Physics, Faculty of Science, King Abdulaziz University, Jeddah, 21589 Saudi Arabia;11. Department of Chemistry, College of Science, Taif University, P.O. Box 11099, Taif, 21944 Saudi Arabia;12. Energy Technol. Program, Department of Specialized Engineering, Faculty of Engineering, Prince of Songkla University, 15 Karnjanavanich Rd., Hat Yai, Songkhla 90110 Thailand;13. Faculty of Applied Sciences, Universiti Teknologi MARA, Cawangan Perlis, 02600 Arau Perlis, Malaysia;14. Chemistry Department, Faculty of Science, Sohag University, Sohag, 82524 Egypt;15. College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua, 321004 China

Abstract:The increasing demand for searching highly efficient and robust technologies in the context of sustainable energy production totally rely onto the cost-effective energy efficient production technologies. Solar power technology in this regard will perceived to be extensively employed in a variety of ways in the future ahead, in terms of the combustion of petroleum-based pollutants, CO2 reduction, heterogeneous photocatalysis, as well as the formation of unlimited and sustainable hydrogen gas production. Semiconductor-based photocatalysis is regarded as potentially sustainable solution in this context. g-C3N4 is classified as non-metallic semiconductor to overcome this energy demand and enviromental challenges, because of its superior electronic configuration, which has a median band energy of around 2.7 eV, strong photocatalytic stability, and higher light performance. The photocatalytic performance of g-C3N4 is perceived to be inadequate, owing to its small surface area along with high rate of charge recombination. However, various synthetic strategies were applied in order to incorporate g-C3N4 with different guest materials to increase photocatalytic performance. After these fabrication approaches, the photocatalytic activity was enhanced owing to generation of photoinduced electrons and holes, by improving light absorption ability, and boosting surface area, which provides more space for photocatalytic reaction. In this review, various metals, non-metals, metals oxide, sulfides, and ferrites have been integrated with g-C3N4 to form mono, bimetallic, heterojunction, Z-scheme, and S-scheme-based materials for boosting performance. Also, different varieties of g-C3N4 were utilized for different aspects of photocatalytic application i. e., water reduction, water oxidation, CO2 reduction, and photodegradation of dye pollutants, etc. As a consequence, we have assembled a summary of the latest g-C3N4 based materials, their uses in solar energy adaption, and proper management of the environment. This research will further well explain the detail of the mechanism of all these photocatalytic processes for the next steps, as well as the age number of new insights in order to overcome the current challenges.
Keywords:g-C3N4  Hydrogen Production  Carbon dioxide reduction  Environmental Remediation  Composite Materials
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