Measurement of Debye-Waller factors by Raman scattering from inter-term excitons and exciton-multiphonon states in FeF2

We have observed inter-term Raman scattering from ⁵T_2g→⁵E_g Frenkel excitons in antiferromagnetic FeF₂. It differs qualitatively from previously observed intra-term scattering in a sharply reduced zero-phonon cross section and the appearance of relatively strong exciton-phonon scattering. Since the Raman process is fully allowed, it is possible to measure excited state Debye-Waller factors, D, and we find $\text{D(Λ}{}_3{}^{\mathrm{+}}\text{+ Λ}{}_4{}^{\mathrm{+}}\text{,}{}^5\text{E}{}_{\mathrm{g}}\text{) = 0.04}$ and $\text{D(Λ}{}_1{}^{\mathrm{+}}\text{,}{}^5\text{E}{}_{\mathrm{g}}\text{) = 0.03}$.