A coordination polymer of (Ph3P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation |
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| Authors: | Nuñez Ana J Shear Lindsey N Dahal Naween Ibarra Ilich A Yoon JiWoong Hwang Young Kyu Chang Jong-San Humphrey Simon M |
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| Affiliation: | Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712-0165, USA. |
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| Abstract: | ![]()
PCM-10 is a porous phosphine coordination material based on Ca(II) and tris(p-carboxylated) triphenylphosphine. The material provides a unique 3-dimensional surface of P(III) Lewis base sites, which is ideal for post-synthetic functionalization. The addition of Au(I) yields an advanced material that can selectively adsorb 1-hexene over n-hexane at room temperature. |
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