Crystal structure and luminescence of antimony(III) chloride complex with anilinium chloride |
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| Authors: | B. V. Bukvetskii T. V. Sedakova A. G. Mirochnik |
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| Affiliation: | (1) Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok, Russia |
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| Abstract: | Crystal structure of (C6H5NH3)3[SbCl5]Cl·H2O is determined by X-ray analysis (a = 9.4155(13) Å, b = 11.4344(16) Å, c = 13.1584(18) Å, α = 113.483(2)°, β = 90.383(2)°, γ = 97.323(2)°, space group P (bar 1), Z = 2, ρcalc = 1.642 g/cm3). The crystal structure is based on [SbCl5]2? anions, anilinium cations (C6H5NH3)+, isolated Cl? anions, and water molecules. Structural features responsible for spectral and luminescent properties of the complex are discussed. |
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| Keywords: | crystal structure antimony(III) aniline luminescence |
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