Diversity in magnetic properties of 3D isomorphous networks of Co(II) and Mn(II) constructed by napthalene-1,4-dicarboxylate |
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| Authors: | Maji Tapas Kumar Kaneko Wakako Ohba Masaaki Kitagawa Susumu |
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| Institution: | Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan. |
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| Abstract: | Two novel 3D isomorphous organic-inorganic hybrid frameworks, M(1,4-napdc)]n ( M = Co(II), and Mn(II), ; 1,4-napdcH2 = napthalene-1,4-dicarboxylic acid) have been hydrothermally synthesized and structurally characterized, and the magnetic results exhibit metamagnetic behaviour (TC = 5.5 K), and a weak antiferromagnetic interaction, which are structurally correlated. |
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