The degree of hybridization in paramagnetic complexes |
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Authors: | M Moreno |
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Institution: | Departamento de Física Fundamental, Facultad de Ciensias, Universidad de Santander, Santander, Spain |
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Abstract: | It is argued that in a series of complexes formed by ions of the same type and having the same geometry and ligand the degree of hybridization tends to decrease when covalency increases. This rule which discards any sp2 explanation for the ligand hybridization has been well verified through series of d9 and s1 complexes. The validity of such a rule, also useful for understanding the behaviour of in some D2h systems, outlines that ligand core polarization effects are negligible in these cases. |
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