Reaction of N-Fmoc aspartic anhydride with glycosylamines: a simple entry to N-glycosyl asparagines |
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| Authors: | Farid M Ibatullin Stanislav I Selivanov |
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| Institution: | a Biophysics Division, Petersburg Nuclear Physics Institute, Gatchina 188300, Russia
b Chemical Department of Petersburg State University, St.-Petersburg, Russia |
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| Abstract: | The reaction of N-Fmoc-aspartic anhydride with glycosyl amines in DMSO selectively leads to the formation of β-substituted products, thus providing a simple and efficient route to N-glycosyl asparagine derivatives, the building blocks for glycopeptide synthesis. |
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