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Synthesis and IR-Spectral Characterization of Mixed-Ligand Solid State Complexes of Some Lanthanoides with Mono-(2-ethylhexyl) Phosphoric Acid
Authors:M Arnaudov  M Milanova  D Todorovsky
Institution:Faculty of Chemistry, University of Sofia , I., J. Bourchier Ave., Sofia, 1126, Bulgaria
Abstract:The synthesis of a new type of complexes of Y, Nd and Er with mono-(2-ethylhexyl) phosphoric acid is reported. The elemental composition, IR-spectral data and thermogravimetric analysis prove the presence of both mono-and bivalent ions of the acid as ligands as well as of NO3-ions. The IR-spectrum is interpreted in comparison with those of other lanthanoid complexes of the same acid.
Keywords:IR-spectrometry  Lanthanoides  Solid state complexes
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