Polarization of the 274 nm Absorption System of Benzoxazole: A Band Contour Analysis |
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Authors: | Robert D. Gordon |
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Affiliation: | Department of Chemistry , Queen's University Kingston , Ontario, Canada , K7L 3N6 |
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Abstract: | Abstract The rotational contour of the origin band of the 274 nm absorption system of benzoxazole vapour has been analyzed and found to be type A. The transition is thus A 1A (π π ?) → X ~ 1A with the transition moment lying close to the long axis of the molecule. Geometrical changes upon excitation are small. |
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Keywords: | benzoxazole electronic spectra polarization |
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