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Raman and Infrared Spectra of Matrix Isolated CO2 and CS2
Authors:A. Loewenschuss  A. Givan
Affiliation:Department of Inorganic and Analytical Chemistry , The Hebrew University , Jerusalem, Israel
Abstract:The matrix isolation infrared and Raman spectra of CO2 and CS2 in solid krypton at 20°K are reported. The fundamental frequencies are only very slightly red-shifted from the free gas values. Isotopic effects are found in both infrared and Raman spectra, whereas site splittings are evident in the infrared only.
Keywords:Matrix isolation  CO2  CS2
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