Microwave spectrum and Structure of Benzenesulphonyl chloride |
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| Authors: | Luis M Boggia Roberto R Filgueira Julio Marañon Oscar M Sorarrain |
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| Institution: | 1. Departamentos de Física y Química Facultad de Ciencias Exactas , Universidad Nacional de La Plata , Argentina;2. Departamentos de Física y Química Facultad de Ciencias Exactas , Universidad Nacional de La Plata , Argentina;3. Carrera del Investigador del CONICET |
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| Abstract: | The microwave spectrum has been investigated for the molecule of Benzenesulphonyl chloride within the 8–18 Ghz frequency region. Several a and b type bands corresponding to the Cl35 and Cl37 Isotopes were observed and assigned. We have also used the CNDO/2 method in order to estimate some molecular parameters and the dipole moment. The theoretical calculation and the experimental data have been joined to derive a reliable structure of the molecule concluding that the Cl is located on the plane of the benzene ring. |
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