The Synthesis,Vibrational Spectra,Electronic Spectra,and Thermal Analysis of Some Mixed Complexes with Planar Dithiooxamides |
| |
| Authors: | M Bellaihou H O Desseyn |
| |
| Institution: | Laboratorium voor Anorganische Scheikunde , R.U.C.A. Universiteit Antwerpen , Groenenborgerlaan 171, 2020, Antwerpen, Belgium |
| |
| Abstract: | Planar Pd(LH)2 complexes (LH2 = H2N C S C S N H2, CH3HNCSCSNHCH3) form mixed polymeric complexes with Ni(II), Cu(II), Zn(II) and Cd(II) in alcalic media, where the planar Pd(LH)2 complexes act as tetradentates with N-coordination. The electronic spectra and thermal behaviour are discussed, a thorough investigation of the i.r. spectra is presented and special attention has been given to the H/D, CH3/CD3 and 58Ni/62Ni, 63Cu/65Cu and 64Zn/68Zn isotopic shifts. |
| |
| Keywords: | Vibrational spectra complexes dithiooxamides |
|
|
