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通过分子复合超分子方法制备高性能高分子材料
引用本文:王琪,李莉,陈宁,刘渊,白时兵.通过分子复合超分子方法制备高性能高分子材料[J].高分子学报,2011(9):932-938.
作者姓名:王琪  李莉  陈宁  刘渊  白时兵
作者单位:高分子材料工程国家重点实验室 四川大学高分子研究所 成都610065
摘    要:分子复合可调控聚合物超分子结构和聚集态结构,提高其性能,是高分子材料制备和高性能化的超分子方法.本文介绍了我们研究组近几年来通过分子复合超分子方法制备新型高分子材料的一些研究工作,如实现PVA的热塑加工,制备高性能熔纺纤维、吹塑薄膜、中空瓶、注塑制品等;制备新型聚合物无卤阻燃剂MCA,大大简化其合成工艺,并具有更高阻燃...

关 键 词:分子复合  高分子高性能化  超分子方法

PREPARATION OF HIGH PERFORMANCE POLYMER MATERIALS THROUGH INTERMOLECULAR COMPLEXATION
WANG Qi,LI Li,CHEN Ning,LIU Yuan,BAI Shibing.PREPARATION OF HIGH PERFORMANCE POLYMER MATERIALS THROUGH INTERMOLECULAR COMPLEXATION[J].Acta Polymerica Sinica,2011(9):932-938.
Authors:WANG Qi  LI Li  CHEN Ning  LIU Yuan  BAI Shibing
Abstract:Intermacromolecular complexation occurring among the macromolecules with complementary structure through the secondary binding forces,e.g.Coulomb forces,hydrogen bonding,van der Waals forces,charge transfer interactions etc.,is an effective supermolecular method for preparation and property enhancing of polymer materials.This paper summarizes our research work on intermolecular complexation in recent years,e.g.,realizing the thermal processing of PVA and developing a series of novel PVA products with high performance,preparing novel halogen free flame retardant,controlling the crystalline structure of POM and effectively improving its notched impact properties and friction and wear properties,etc.
Keywords:Intermolecular complexation  High performance polymer  Supermolecular method
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