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Facile Fabrication of Bicomponent CoO/CoFe2O4‐N‐Doped Graphene Hybrids with Ultrahigh Lithium Storage Capacity
Authors:Changtai Zhao  Chang Yu  Shaohong Liu  Juan Yang  Xiaoming Fan  Jieshan Qiu
Institution:Carbon Research Laboratory, Liaoning Key Lab for Energy Materials and Chemical Engineering, State Key Lab of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian, P. R. China
Abstract:A facile strategy is developed to fabricate bicomponent CoO/CoFe2O4‐N‐doped graphene hybrids (CoO/CoFe2O4‐NG). These hybrids are demonstrated to be potential high‐performance anodes for lithium‐ion batteries (LIBs). The CoO/CoFe2O4 nanoplatelets are finely dispersed on the surface of N‐doped graphene nanosheets (CoO/CoFe2O4‐NG). The CoO/CoFe2O4‐NG electrode exhibits ultrahigh specific capacity with 1172 mA h g?1 at 500 mA g?1 and 970 mA h g?1 at 1000 mA g?1 as well as excellent cycle stability due to the synergetic effects of N‐doped graphene and CoO/CoFe2O4 nanoplatelets. The well‐dispersed bicomponent CoO/CoFe2O4 is responsible for the high specific capacity. The N‐doped graphene with high specific surface area has dual roles: to provide active sites for dispersing the CoO/CoFe2O4 species and to function as an electrical conducting matrix for fast charge transfer. This method provides a simple and efficient way to configure the hybridized electrode materials with high lithium storage capacity.
Keywords:CoO/CoFe2O4  graphene  lithium‐ion batteries  electrodes  hybrid materials  nanoplatelets
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