Synthesis of isomeric 2-oxazolidinones from (1<Emphasis Type="Italic">R</Emphasis>,2<Emphasis Type="Italic">R</Emphasis>)-and (1<Emphasis Type="Italic">S</Emphasis>,2<Emphasis Type="Italic">S</Emphasis>)-2-amino-1-(4-nitrophenyl)-1,3-propanediols |
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Authors: | M Madesclaire V P Zaitsev J V Zaitseva S Kh Sharipova |
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Institution: | (1) Faculté de Farmacie, Université d’Auvergne, Clermont-Ferrand, France;(2) Samara State University, 443011 Samara, Russia |
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Abstract: | A synthesis is reported for (4R,5R)-and (4S,5S)-4-hydroxymethyl-5-(4-nitrophenyl)oxazolidin-2-ones and (1′R,4R)-and (1′S,4S)-4-hydroxy(4-nitrophenyl)methyl]oxazolidin-2-ones from (1R,2R)-and (1S,2S)-2-amino-1-(4-nitrophenyl)-1,3-propanediols. The effect of the experimental conditions on the formation of these compounds
was studied.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1562–1570, October, 2007. |
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Keywords: | (1R 2R)-and (1S 2S)-2-amino-1-(4-nitrophenyl)-1 3-propanediols (4R 5R)-and (4S 5S)-4-hydroxymethyl-5-(4-nitrophenyl)oxazolidin-2-ones (1′ R 4R)-and (1′ S 4S)-4-[hydroxy(4-nitrophenyl)-methyl]oxazolidin-2-ones |
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