Branched carbon-rich luminescent multinuclear platinum(II) and palladium(II) alkynyl complexes with phosphine ligands |
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| Authors: | Chi-Hang Tao Vivian Wing-Wah Yam |
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| Affiliation: | Centre for Carbon-Rich Molecular and Nano-Scale Metal-Based Materials Research, Department of Chemistry, and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong, China |
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| Abstract: | In this review, the synthesis, electronic absorption and luminescent properties of a series of branched alkynylpalladium(II) and -platinum(II) phosphine complexes with different alkynyl backbones and some of their structurally related complexes in the literature will be discussed. With the growing research interest in the potential application of these complexes in the field of non-linear optics (NLO), the two-photon absorption (TPA) properties and the corresponding structure–property relationships of selected luminescent branched platinum(II) bis-alkynyl complexes will also be described. |
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