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Directly assembled CdSe quantum dots on TiO2 in aqueous solution by adjusting pH value for quantum dot sensitized solar cells
Authors:J. Chen  D.W. Zhao  J.L. Song  X.W. Sun  W.Q. Deng  X.W. Liu  W. Lei
Affiliation:1. School of Electronic Science and Engineering, Southeast University, Nanjing 210096, China;2. School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798, Singapore;3. Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Science, Nanyang Technological University, Singapore 637616, Singapore
Abstract:We report an improved quantum dot sensitized solar cell (QDSSC) by loading mercaptopropionic acid (MPA)-capped CdSe QDs on TiO2 film in aqueous solution. Under suitable pH value, a power conversion efficiency of 1.19% and an incident photon to current conversion efficiency of 26% for the QDSSC were obtained at AM1.5G irradiation. The improved performance of QDSSC is attributed to the large loading and good coverage of QDs on TiO2 film with optimal pH value.
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