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New Temperature Integral Approximate Formula for Non-isothermal Kinetic Analysis
Authors:T. Wanjun  L. Yuwen  Z. Hen  W. Zhiyong  W. Cunxin
Affiliation:(1) College of Chemistry and Molecular Science, Wuhan University, Wuhan, 430072, P. R. China
Abstract:A new approximate formula for temperature integral is proposed. The linear dependence of the new fomula on x has been established. Combining this linear dependence and integration-by-parts, new equation for the evaluation of kinetic parameters has been obtained from the above dependence. The validity of this equation has been tested with data from numerical calculating. And its deviation from the values calculated by Simpson's numerical integrating was discussed. Compared with several published approximate formulae, this new one is much superior to all other approximations and is the most suitable solution for the evaluation of kinetic parameters from TG experiments. This revised version was published online in August 2006 with corrections to the Cover Date.
Keywords:non-isothermal kinetic analysis  temperature integral  approximate formula  TG
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